%0 Journal Article %1 Bodach2018 %A Bodach, Alexander %A Fink, Lothar %A Schmidt, Martin U. %D 2018 %J Chemical Communications %K crystal-structure iso-butyllithium xrpd %P 10734--10737 %R 10.1039/c8cc05918g %T Crystal structures of ordered and plastic-crystalline phases of iso-butyllithium by X-ray powder diffraction %U http://dx.doi.org/10.1039/c8cc05918g %V 54 %X Donor-unsupported iso-butyllithium consists of hexamers with an ordered triclinic structure at −80 °C (α-phase). At ambient temperature, the compound exists as an orthorhombic, remarkably stable, plastic-crystalline γ-phase, which is built by disordered hexamers adopting a distorted face-centred cubic packing. Both structures were determined by X-ray powder diffraction. Additionally, an intermediate β-phase is observed.

@article{Bodach2018, abstract = {{Donor-unsupported iso-butyllithium consists of hexamers with an ordered triclinic structure at −80 °C (α-phase). At ambient temperature, the compound exists as an orthorhombic, remarkably stable, plastic-crystalline γ-phase, which is built by disordered hexamers adopting a distorted face-centred cubic packing. Both structures were determined by X-ray powder diffraction. Additionally, an intermediate β-phase is observed.}}, added-at = {2019-03-11T21:00:05.000+0100}, author = {Bodach, Alexander and Fink, Lothar and Schmidt, Martin U.}, biburl = {https://www.bibsonomy.org/bibtex/28d4622c7bb278fb102644960083a5624/fairybasslet}, citeulike-article-id = {14634561}, citeulike-linkout-0 = {http://dx.doi.org/10.1039/c8cc05918g}, day = 07, doi = {10.1039/c8cc05918g}, interhash = {2776058f7bfe00c6a916d91784f40082}, intrahash = {8d4622c7bb278fb102644960083a5624}, issn = {1359-7345}, journal = {Chemical Communications}, key = {Bodach2018}, keywords = {crystal-structure iso-butyllithium xrpd}, month = sep, pages = {10734--10737}, posted-at = {2018-09-10 12:03:04}, priority = {2}, timestamp = {2019-03-11T21:06:37.000+0100}, title = {{Crystal structures of ordered and plastic-crystalline phases of iso-butyllithium by X-ray powder diffraction}}, url = {http://dx.doi.org/10.1039/c8cc05918g}, volume = 54, year = 2018 }